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Glossary · Units

Calorific value (HHV / LHV)

The heat released by complete combustion of a unit quantity of fuel; the higher (gross) value includes condensation heat of water vapour, the lower (net) value excludes it.

A fuel's calorific value or heating value can be stated in two ways:

  • Higher heating value (HHV, gross calorific value): assumes combustion products are cooled to 25 °C and the water formed condenses, releasing its latent heat (about 2.44 MJ per kg of water)
  • Lower heating value (LHV, net calorific value): assumes water leaves as vapour, so latent heat is not counted
HHV = LHV + m_water x h_fg (h_fg ≈ 2.44 MJ/kg at 25 °C)
LHV/HHV ratios: hydrogen 0.85 (120 / 141.8 MJ/kg); natural gas about 0.90 (50 / 55.5 MJ/kg methane); diesel/gasoline about 0.93–0.94; coal 0.95–0.97
Wood at 20% moisture: LHV about 14–15 MJ/kg; dry wood about 18–19 MJ/kg

Conventions differ by region and sector: European statistics and engine or turbine efficiencies usually use LHV; US statistics (EIA) and gas billing use HHV. This explains why condensing boilers can be advertised as "107% efficient" on an LHV basis (about 97% HHV) and why a CCGT rated 60% LHV is about 54% HHV. Hydrogen comparisons are particularly sensitive: electrolyser efficiency quoted on HHV appears about 18% higher than on LHV.

Moisture strongly reduces the net value of biomass and lignite. Convert fuel quantities with the fuel energy content calculator.

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  • Heat rate

    The fuel energy a thermal power plant consumes per kWh of electricity generated; the inverse of efficiency, usually in BTU/kWh or kJ/kWh.

  • Natural gas

    A fossil fuel composed mainly of methane, used for power generation, industrial and residential heat, and as a chemical feedstock for hydrogen and ammonia.

  • Green hydrogen

    Hydrogen produced by splitting water in an electrolyser powered by renewable electricity, with near-zero direct CO2 emissions.

  • Tonne of oil equivalent (toe)

    A conventional energy unit equal to 41.868 GJ (10 Gcal, 11.63 MWh), the nominal heat content of one tonne of crude oil, used in energy balances.

  • BTU (British thermal unit)

    A traditional unit of heat, approximately the energy needed to raise one pound of water by one degree Fahrenheit; 1 BTU (IT) = 1,055.06 J.